Directorio
Anatoli Iatsimirski
Correo: iatsimirski46@comunidad.unam.mx
Doctor en Química (Ph.D.).
Doctor en Ciencias (D.Sc.).
[L] Química Inorgánica (teoría y laboratorio)
[Pg] Cinética
- Química Bioinorgánica
- Reconocimiento molecular de biomoléculas y aniones.
Estudios de reconocimiento molecular con moléculas biológicas be baja masa molar (alcaloides, antibióticos, etc.); desarrollo de “hidrolasas artificiales” (catalizadores de la ruptura de ésteres, fosfoésteres incluyendo ADN y ARN y péptidos en disolución acuosa); reconocimiento molecular de aniones y biomoleculas con receptores ácidos de Lewis.
- Programa de Maestría y Doctorado en Ciencias Químicas de la UNAM
- En 1989 obtuvo el título de Profesor por resolución del Comité Estatal de Educación Nacional de la URSS.
- En 1992 recibió “The Twentieth Century Award for Achievement” de Cambridge International Biographical Centre, UK.
- Obtuvo la Cátedra de Excelencia Nivel II, otorgada por el CONACyT para el periodo de noviembre 1992 a noviembre 1994.
- En el 2000 recibió Journals Grant for International Authors otorgado por Royal Society of Chemistry, UK.
- Investigador Nacional Nivel III otorgado en 1994.
- Premio Nacional de Química “Andrés Manuel del Río” en Investigación, 2017.
Ortega-Valdovinos, L. R., Chino-Cruz, J. G., & Yatsimirsky, A. K.* (2023). Zwitterion–neutral form equilibria and binding selectivity of pyridineboronic acids. Organic And Biomolecular Chemistry, 21(36), 7395-7409.
DOI:10.1039/d3ob01211e
González-Méndez, I., Sorroza-Martínez, K., González-Sánchez, I., Gracia-Mora, J., Bernad‐Bernad, M. J., Cerbón, M., Rivera, E.*, & Yatsimirsky, A. K.* (2023). Exploring the influence of spacers in EDTA–Β-Cyclodextrin dendrimers: physicochemical properties and in vitro biological behavior. International Journal of Molecular Sciences, 24(19), 14422.
DOI:10.3390/ijms241914422
Ortega-Valdovinos, L. R., & Yatsimirsky, A. K.* (2023). Probing the Role of the Bridging Nitrogen in the Signaling Mechanism of an Anthracene–Boronic Acid Sugar Sensor and a Different Version of the PET-Based Mechanism. Journal of Organic Chemistry, 88(7), 4662-4674.
DOI:10.1021/acs.joc.3c00129
Valdes-García, J., Zamora-Moreno, J., Salomón-Flores, M. K., Martínez-Otero, D., Barroso-Flores, J., Yatsimirsky, A. K., Bazany-Rodríguez, I. J., & Dorazco-González, A.* (2023). Fluorescence Sensing of Monosaccharides by Bis-boronic Acids Derived from Quinolinium Dicarboxamides: Structural and Spectroscopic Studies. Journal of Organic Chemistry, 88(4), 2174-2189.
DOI:10.1021/acs.joc.2c02590
Komkova, M.*, Valeev, R., Kolyagin, Y., Andreev, E., Beltukov, A., Nikitina, V., Yatsimirsky, A., Karyakin, A. & Eliseev, A.* (2022). Solid-state survey of boronate-substituted polyaniline: on the mechanism of conductivity, electroactivity, and interactions with polyols. Materials Today Chemistry, 26, 101070.
DOI:10.1016/j.mtchem.2022.101070
Martínez‐Aguirre, M. A., Medrano, F., Ramírez‐Rave, S. & Yatsimirsky, A. K.* (2022). Analysis of the relative stability of trigonal and tetrahedral boronate cyclic esters in terms of boronic acid and diol acidities and the strain release effect. Journal of Physical Organic Chemistry.
DOI:10.1002/poc.4425
Martínez-Aguirre, M. A., Ortega-Valdovinos, L. R., Villamil-Ramos, R. & Yatsimirsky, A. K.* (2022). Anion Recognition by Benzoxaborole. The Journal of Organic Chemistry, 87(12), 7734-7746.
DOI:10.1021/acs.joc.2c00324
Ramírez-Rave, S., Flores-Alamo, M. & Yatsimirsky, A. K.* (2022). Structures, solvatochromism, protonation and photoswitching of tetra-(ortho)substituted azobenzenes bearing 3,5-dimethoxy groups. New Journal of Chemistry, 46(13), 5996-6008.
DOI:10.1039/d1nj05699a
Ortega-Valdovinos, L. R., Valdes-García, J., Bazany-Rodríguez, I. J., Lugo-González, J. C., Dorazco-González, A., & Yatsimirsky, A. K.* (2021). Anion recognition by anthracene appended ortho-aminomethylphenylboronic acid: a new PET-based sensing mechanism. New Journal of Chemistry, 45(34), 15618-15628.
DOI:10.1039/d1nj02684d
Martínez-Aguirre, M. A., Flores Alamo, M., Elisa Trejo-Huizar, K., & Yatsimirsky, A. K.* (2021). Boronic acid complexes with amino phenolic N,O-ligands and their use for non-covalent protein fluorescence labeling. Bioorganic Chemistry, 113.
DOI:10.1016/j.bioorg.2021.104993
Ramírez-Rave, S., Bernad-Bernad, M. J., Gracia-Mora, J., & Yatsimirsky, A. K. (2020). Recent Advances in Application of Azobenzenes Grafted on Mesoporous Silica Nanoparticles in Controlled Drug Delivery Systems Using Light as External Stimulus. Mini-Reviews in Medicinal Chemistry, 20(11), 1001-1016.
DOI:10.2174/1389557519666190904145355
Trejo-Huizar, K. E., Jiménez-Sánchez, A., & Yatsimirsky, A. K. (2020). Composition, stability and fluorescence properties of metal complexes of an aza-flavonol analog 1-methyl-2-phenyl-3-hydroxy-4(1H)-quinolone in aqueous solution. Inorganica Chimica Acta, 505.
DOI:10.1016/j.ica.2020.119471
Martínez-Aguirre, M. A., Flores-Alamo, M., Medrano, F., & Yatsimirsky, A. K. (2020). Examination of pinanediol–boronic acid ester formation in aqueous media: relevance to the relative stability of trigonal and tetrahedral boronate esters. Organic and Biomolecular Chemistry, 18(14), 2716-2726.
DOI:10.1039/d0ob00201a
Lopéz-Martínez, L. M., García-Elías, J., Ochoa-Terán, A., Ortega, H. S., Ochoa-Lara, K., Montaño-Medina, C. U., Yatsimirsky, A. K., Ramírez, J. Z., Labastida-Galván, V., & Ordoñez, M. (2020). Synthesis, characterization and anion recognition studies of new fluorescent alkyl bis(naphthylureylbenzamide)-based receptors. Tetrahedron, 76(2).
DOI:10.1016/j.tet.2019.130815
Lugo, C., Gomez-Tagle, P.*, Flores-Alamo, M., & Yatsimirsky, A.* (2020). Mechanistic study of carboxylic acid and phosphate ester cleavage by oximate metal complexes surpassing the limiting reactivity of highly basic free oximate anions. Dalton Transactions.
DOI:10.1039/C9DT04733F
Villamil-Ramos, R., Gómez-Tagle, P., Aguilar-Cordero, J. C., & Yatsimirsky, A. K. (2019). Spectrophotometric, fluorimetric and electrochemical selective pyrophosphate/ATP sensing based on the dimethyltin(IV)-tiron system. Analytica Chimica Acta, 1057, 51-59.
DOI:10.1016/j.aca.2019.01.020
Vallejo Narváez, W. E., Jiménez, E. I., Cantú-Reyes, M., Yatsimirsky, A. K., Hernández-Rodríguez, M., & Rocha-Rinza, T. (2019). Stability of doubly and triply H-bonded complexes governed by acidity-basicity relationships. Chemical Communications, 55(11), 1556-1559.
DOI:10.1039/c8cc06967k
Ramírez-Rave, S., Bernad-Bernad, M., Gracia-Mora, J.*, & Yatsimirsky, A.* (2019). Recent Advances in Application of Azobenzenes Grafted on Mesoporous Silica Nanoparticles in Controlled Drug Delivery Systems Using Light as External Stimulus. Mini-Reviews in Medicinal Chemistry, 19.
DOI:10.2174/1389557519666190904145355
Martínez-Aguirre, M. A., Flores-Alamo, M., & Yatsimirsky, A. K. (2018). Thermodynamic and structural study of complexation of phenylboronic acid with salicylhydroxamic acid and related ligands. Applied Organometallic Chemistry, 32(8).
DOI:10.1002/aoc.4405
Ramírez-Zatarain, S. D., Ochoa-Terán, A., Reynoso-Soto, E. A., Miranda-Soto, V., Félix-Navarro, R. M., Pina-Luis, G., & Yatsimirsky, A. K. (2017). Selective interaction of N,N-bis(aminobenzyl)naphthalenediimides with fluoride anion. Supramolecular Chemistry, 29(6), 446-454.
DOI:10.1080/10610278.2016.1266360
Martínez-Aguirre, M. A., Otero, D. M., Álvarez-Hernández, M. L., Torres-Blancas, T., Dorazco-González, A., & Yatsimirsky, A. K. (2017). Anion and sugar recognition by 2,6-pyridinedicarboxamide bis-boronic acid derivatives. Heterocyclic Communications, 23(3), 171-180.
DOI:10.1515/hc-2017-0054
Lugo-González, J. C., Gómez-Tagle, P., Huang, X., M. Del Campo, J., & Yatsimirsky, A. K. (2017). Substrate specificity and leaving group effect in ester cleavage by metal complexes of an oximate nucleophile. Inorganic Chemistry, 56(4), 2060-2069.
DOI:10.1021/acs.inorgchem.6b02739
Nikitina, V. N., Zaryanov, N. V., Kochetkov, I. R., Karyakina, E. E., Yatsimirsky, A. K., & Karyakin, A. A. (2017). Molecular imprinting of boronate functionalized polyaniline for enzyme-free selective detection of saccharides and hydroxy acids. Sensors and Actuators, B: Chemical, 246, 428-433.
DOI:10.1016/j.snb.2017.02.073
Trejo-Huizar, K. E., Jiménez-Sánchez, A., Martínez-Aguirre, M. A., & Yatsimirsky, A. K. (2016). Fluorescence ratiometric sensing of polyols by phenylboronic acid complexes with ligands exhibiting excited-state intramolecular proton transfer in aqueous micellar media. Journal of Luminescence, 179, 393-401.
DOI:10.1016/j.jlumin.2016.07.007
Solís-Delgado, L. E., Ochoa-Terán, A., Yatsimirsky, A. K., & Pina-Luis, G. (2016). Colorimetric and fluorescent determination of fluoride using a novel naphthalene diimide boronic acid derivative. Analytical Letters, 49(14), 2301-2311.
DOI:10.1080/00032719.2016.1147575
Ruiz Kubli, M., & Yatsimirsky, A. K. (2016). Phosphodiester cleavage by trivalent lanthanides in the presence of native cyclodextrins. Inorganica Chimica Acta, 440, 9-15.
DOI:10.1016/j.ica.2015.10.039
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